1 machine 2 nic cards 2 static ips, HELP

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So ive looked all over the web well almost, cant say all i havent found a fix that works.
Ive tried all the sites with vanity domains and this and that and i have nothing.

So what i ask here is this
whats the exact process one would take to setup one machine with xampp, 2 network cards each having their own static ip, and have their own domain name and have it so each domain will go to its folder within the htdocs file of xampp.
Sorry if this id confusing its been a rough long week.

Other then setting this up for two it works just fine for the one.

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oh more info when you goto either website they both point to where the original site index would have been

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well i lol fixed the issue i was having all the site had me changing a windows file, without doing so the direction worked!!!!!! So nevermind and ill post real questions soon lol