It seems to be the application XAMPP Control which does not work on PPC processors.
To start the servers you need not to uninstall XAMPP 1.7.2 and reinstall XAMPP 0.7.4.
Please open the Terminal, type the following line, and XAMPP will start
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sudo /Applications/XAMPP/xampp start
You will be asked for your password in the script
... that's all.
Moodle4Mac with XAMPP - http://download.moodle.org/macosx