Seems to be that any new file I place into a folder which has been added to the httpd.conf and Hosts files cannot be accessed through my Browser and Server. The Vhost configuration is the absolute minimum since the server never sees the Internet and I only use it for testing local stuff. And the XAMPP is default (with the exception of the vhosts)
I can't seem to find any specific instance where this has been a problem. I can access the old files perfectly, but not the newly added ones. Rt-click, Properties shows nothing special on the file attributes. They are the same as files which do actually display.
Also, if I attempt to access them through localhost/folder/filename.ext, I get the same results, file not found.